Product ID:SUPER 77 SPRAY ADHESIVE
MSDS Date:11/08/1990
FSC:8040
NIIN:00-266-0824
Status Code:A
MSDS Number: CLKVP

MINNESOTA MINING AND MFG CO

3M CENTER
SAINT PAUL, MN 55144-1000
US

Emergency Phone: 800-253-3456

Info Phone: 800-364-3557 / 651-737-6501(24 HR)

Preparer: RYAN MICKELSON

Cage: 76381

MINNESOTA MINING AND MFG CO, DBA 3M

SAINT PAUL, MN 55144-1000 US

Telephone: 866-556 5712 / 612-733-1110

Cage: 76381

N-HEXANE

CAS: 110-54-3

RTECS: MN9275000

OSHA PEL 1800 MG/M3;500 PPM

EPA Report Quantity: 1 LB

DOT Report Quantity: 1 LB

HEXANE (OTHER ISOMERS)

CYCLOHEXANE

CAS: 110-82-7

RTECS: GU6300000

OSHA PEL 1050 MG/M3;300 PPM

ACGIH TLV: 1030 MG/M3;300 PPM

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

PROPANE

CAS: 74-98-6

RTECS: TX2275000

OSHA PEL 1800 MG/M3;1000 PPM

ISOBUTANE

CAS: 75-28-5

RTECS: TI4300000

DIMETHYL ETHER

CAS: 115-10-6

RTECS: PM4780000

NON-VOLATILE COMPONENTS

NON-VOLATILE COMPONENTS-N.J.

Effects of Overexposure:EYE CONTACT: MAY CAUSE EYE IRRITATION UPON
DIRECT CONTACT. SKIN CONTACT: PROLONGED AND REPEATED SKIN CONTACT
MAY DEFAT SKIN LEADING TO IRRITATION AND DERMATITIS. N-HEXANE MAY
BE ABSORBED THROUGH THE SKIN IN HARMFUL AMOUNTS. INHALATION:
VAPOR OVEREXPOSURE MAY CAUSE REPIRATORY SYSTEM IRRITATION AND
TEMPORARY NERVOUS SYSTEM IMPAIRMENT. SYMPTOMS MAY INCLUDE WEAKNESS,
DIZZINESS, HEADACHE, NAUSEA AN D FACIAL NUMBNESS. THERE ARE
REPORTED INSTANCES WHERE EXPOSURE TO H-HEXANE VAPOR CONCENTRATIONS
IN EXCESS OF 800 PPM CAUSED PERIPHERAL NERVE DAMAGE. GROSS
OVEREXPOSURE SUCH AS IS CAUSED BY INTENTIONAL INHALATION OF
CONCENTRATED VAPORS IN A

First Aid:EYE CONTACT: IMMEDIATELY FLUSH EYES WITH PLENTY OF WATER
FOR AT LEAST 10 MINUTES. CALL A PHYSICIAN. SKIN CONTACT: WASH
AFFECTED AREA WITH SOAP AND WATER. INHALATION: MOVE TO
UNCONTAMINATED AIR . CALL A PHYSICIAN. IF SWALLOWED: IF
SWALLOWED, DO NOT INDUCE VOMITING. CALL A PHYSICIAN IMMEDIATELY.
OTHER FIRST AID: NONE

Flash Point Method:TCC
Flash Point:=-45.4C, -50.F
Extinguishing Media:CO2, FOAM, DRY CHEMICAL
Fire Fighting Procedures:FIRE FIGHTERS SHOULD BE EQUIPPED WITH
SELF-CONTAINED BREATHING APPARATUS WHEN FIGHTING FIRES INVOLVING
THIS MATERIAL.
Unusual Fire/Explosion Hazard:EXTREMELY FLAMMABLE. (TREAT AS FLAMMABLE
PRESSURIZED CONTAINER) OVERHEATED, CLOSED CONTAINER ADJACENT TO
FIRE COULD EXPLODE DUE TO PRESSURE BUILD UP.

Spill Release Procedures:IF CANS RUPTURE: EXTINGUISH ALL IGNITION
SOURCES. VENTILATION AREA. OBSERVE PRECAUTIONS FROM OTHER SECTIONS.
CONTAIN SPILL. COVER WITH ABSORBENT MATERIALS AS NEEDED. COLLECT
SPILLED MATERIAL. PLACE IN A U.S. DEPT. OF TRANSPORTATION APPROVED
METAL CONTAINER, AND SEAL.

Handling and Storage Precautions:PRECAUTIONARY INFORMATION FOR
INDUSTRIAL OR PROFESSIONAL USE ONLY. KEEP PRODUCT AND ITS VAPORS
AWAY FROM HEAT, SPARKS, FLAMES AND OTHER SOURCES OF IGNITION.
EXTINGUISH AND DO NOT IGNITE ANY FLAME IN THE IMMEDIATE WORK AREA.
THE VAPORS RELEASED BY THIS PRODUCT CAN EASILY BE IGNITED AND BURN
EXPLOSIV

Respiratory Protection:NIOSH/MSHA APPROVED RESPIRATOR APPROPRIATE FOR
EXPOSURE OF CONCERN .
Ventilation:USE ONLY IN AREAS ADEQ VENT W/ ENOUGH AIR MOVEMENT TO
REMOVE VAPORS & PREVENT VAPOR BUILD-UP.CONSULT LOCAL (SEE SUP DATA
Protective Gloves:IMPERVIOUS GLOVES
Eye Protection:CHEMICAL WORKERS GOGGLES
Supplemental Safety and Health
SIGNS & SYMPTOMS OF OVEREXPOSURE:OR DEATH,MEK IS A POTENTIAL
EMBRYO/FETOTOXIN BASED ON LAB STUDIES.THERE IS NO EVIDENCE OF
REPRODUCTIVE EFFECTS ASSOCIATED W/ HUMAN EXPOS TO
MEK.VENT:SAFETY/HEALTH AUTH ORITIES IF ADDITIONAL GUIDANCE IS
NECESSARY .

Vapor Density:2.97 AIR=1
Spec Gravity:0.702 WATER=1
VOC Pounds/Gallon:527
Evaporation Rate & Reference:1.90 ETHER=1
Solubility in Water:NIL
Appearance and Odor:LIGHT CREAM COLORED, LIQUID IN AEROSOL,
SWEET/FRUITY ODOR
Percent Volatiles by Volume:75

Stability Indicator/Materials to Avoid:YES
Stability Condition to Avoid:DO NOT STORE AT TEMPERATURES ABOVE 120
DEGREES F. DO NOT PUNCTURE OR INCINERATE CONTAINER.
Hazardous Decomposition Products:CO, CO2 AND SMOKE PARTICLES WHEN
SUBJECTED TO EXCESSIVE HEAT OR FLAME.

Waste Disposal Methods:INCINERATE ABSORBED AND PARTIALLY FULL CANS
AFTER MIXING WITH FLAMMABLE MATERIAL IN A PERMITTED HAZARDOUS
WASTER FACILITY. DO NOT PUNCTURE OR BURN CANS IN HOUSEHOLD
INCINERATOR. DISPOSE OF EMPTY CANS IN A SANITARY LANDFILL.
DISPOSAL SHOULD BE IN ACCORDANCE WITH APPLICABLE REGULATIONS. U.S.
EPA HAZAR DOUS WASTE NUMBER: D001

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.